Reactivity and Selectivity of Bowl-Shaped Polycyclic Aromatic Hydrocarbons: Relationship to C60
نویسندگان
چکیده
منابع مشابه
Reactivity and Selectivity of Bowl-Shaped Polycyclic Aromatic Hydrocarbons: Relationship to C60.
The Diels-Alder reactivity of different bowl-shaped polycyclic aromatic hydrocarbons (namely, corannulene, cyclopentacorannulene, diindenochrysene, hemifullerene, and circumtrindene) has been explored computationally within the DFT framework. To this end, both the increase in reactivity with the size of the buckybowl and complete [6,6]-regioselectivity in the process have been analyzed in detai...
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Bowl-in-bowl stacking of buckybowls on a copper surface is observed via scanning tunneling microscopy (STM) at low temperatures and characterized by density functional theory (DFT) calculations.
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Polycyclic aromatic hydrocarbons are a class of potentially hazardous chemicals of environmental and health concern. PAHs are one of the most prevalent groups of contaminants found in soil. Biodegradation of complex hydrocarbon usually requires the cooperation of more than single specie. In this research biotreatment of PAH (phenanthrene) was studied in a solid-phase reactor using indigenou...
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ژورنال
عنوان ژورنال: Chemistry - A European Journal
سال: 2015
ISSN: 0947-6539
DOI: 10.1002/chem.201502248